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BS EN IEC 60480:2019 – TC:2020 Edition

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Tracked Changes. Specifications for the re-use of sulphur hexafluoride (SF6) and its mixtures in electrical equipment

Published By Publication Date Number of Pages
BSI 2020 125
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IEC 60480:2019 provides criteria for the re-use of sulphur hexafluoride (SF 6) and its mixtures after recovery and reclaiming from electrical equipment (e.g. for maintenance, at the end-of-life). Sulphur hexafluoride (SF 6), nitrogen (N 2) and carbon tetrafluoride (CF 4), are gases commonly used for electrical equipment. Taking into account environmental concerns, particular attention is paid to re-use criteria for SF 6 and its mixtures with N 2 and CF 4 for its use in electrical equipment. Procedures for recovering and reclaiming used SF 6 and its mixtures are outside the scope of this document and are described in IEC 62271-4. This document provides several annexes on the description of the different methods of analysis, on by-products, on the procedure for evaluating the potential health effects from by-products, on cryogenic reclaiming of SF 6, and on reclaiming recommendations. Storage, transportation and disposal of SF 6 and its mixtures are outside the scope of this document and are covered by IEC 62271-4. Procedures to determine SF6 leakages are described in IEC 60068-2-17. For the purposes of this document, the complementary gases used in SF 6 mixtures will be limited to N 2 or CF 4. This third edition cancels and replaces the second edition, published in 2004. This edition constitutes a technical revision. This edition includes the following significant technical changes with respect to the previous edition: • specifications for the re-use of SF 6 have been confirmed; • specifications for the re-use of SF 6 mixtures, namely SF 6/N 2 and SF 6/CF 4 mixtures are included; • as a result of a new repartition of annexes in IEC 60376, IEC 60480 and IEC 62271-4, this new edition now contains the following five annexes: – Annex A: Description of methods of analysis (on-site and laboratory); – Annex B: By–products of SF 6 and its mixtures; – Annex C: Procedure for evaluating the potential effects on health from by products of SF 6 and its mixtures; – Annex D: Reclaiming recommendations. – Annex E: Cryogenic reclaiming of SF 6;

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PDF Pages PDF Title
1 compares BS EN IEC 60480:2019
2 TRACKED CHANGES
Text example 1 — indicates added text (in green)
73 undefined
76 Annex ZA(normative)Normative references to international publicationswith their corresponding European publications
78 English
CONTENTS
81 FOREWORD
83 1 Scope
2 Normative references
84 3 Terms and definitions
85 4 Contaminants and their sources
4.1 General
4.2 Contaminants from handling and use
4.3 SF6 by-products in equipment that only have an insulating function
Tables
Table 1 – SF6 contaminants
86 4.4 SF6 by-products in switching equipment
4.5 SF6 by-products from internal arcs
4.6 SF6 mixtures specific by-products
5 Specifications for re-use of SF6
Table 2 – Specifications for re-use of SF6
87 6 Specifications for re-use of SF6 mixtures
7 Reclaiming of SF6 and SF6 mixtures
7.1 Feasibility and process
Table 3 – Specifications for re-use of SF6/N2 mixtures
Table 4 – Specifications for re-use of SF6/CF4 mixtures
88 Table 5 – General contaminants and methods for their removal
Table 6 – Typical adsorbents for various SF6 contaminants
89 Figures
Figure 1 – Decision flow chart for recovered SF6
90 7.2 Detection techniques for checking the quality of the gases
7.2.1 General
7.2.2 On-site analysis
91 7.2.3 Laboratory analysis
Table 7 – On-site methods
92 8 Handling, storage and transportation (informative)
9 Safety and first aid
9.1 General safety rules
9.1.1 General
Table 8 – Laboratory methods
93 9.1.2 Protection of personnel
Table 9 – Measures when working with SF6 electric power equipment
94 9.1.3 Handling of contaminated safety equipment and tools
Table 10 – Safety measures when opening or accessing gas compartments
95 9.1.4 Pressurized equipment and tools or measuring devices
9.1.5 Personal safety and protective equipment
Table 11 – Neutralizing solutions
96 9.1.6 Facilities and services
9.2 Additional safety measures in case of abnormal release of SF6 due to external fire or internal arc fault
97 9.3 First aid equipment and treatment
9.3.1 General
9.3.2 Irritation of the skin
Table 12 – Additional safety measures
98 9.3.3 Irritation of the eyes
9.3.4 Breathing difficulty
10 Environmental aspects
99 Annexes
Annex A (informative) Description of methods of analysis (on-site and laboratory)
A.1 Sampling
A.1.1 General
A.1.2 On-site sampling connection
A.1.3 Sample cylinder for laboratory analysis
100 A.1.4 Sampling methods for laboratory analysis
Figure A.1 – One-sampling cylinder method set-up
Figure A.2 – Two-sampling cylinder method set-up
101 A.2 On-site analysis
A.2.1 General
A.2.2 SF6 concentration meter
A.2.3 Hygrometers
102 A.3 Laboratory analysis
A.3.1 Gas chromatography
103 Figure A.3 – Example of a gas chromatogram in one print out showing the different possible by-products after decomposition
104 A.3.2 Infrared spectroscopy
Figure A.4 – Typical GCMS chromatogram of decomposed SF6/CF4 mixture
105 Table A.1 – Peak absorption of SF6 and contaminants
106 Figure A.5 – IR spectrum of contaminated SF6
107 Annex B (informative) By-products of SF6 and its mixtures
B.1 Decomposition of SF6 and its mixtures
B.1.1 General
B.1.2 Behaviour of SF6 in an electric arc
109 B.1.3 SF6 decomposition with low current discharges
B.1.4 Catalytic decomposition of SF6 (high-temperature behaviour)
B.2 Corrosion behaviour of SF6 and its by-products
B.3 Measures for the removal of by-products
110 B.4 Physiological characteristics of by-products
111 Annex C (informative) Procedures for evaluating the potential effects on health from by-products of SF6 and its mixtures
C.1 General
C.2 Formation and health effects of SF6 by-products
C.2.1 Formation of SF6 by-products
112 C.2.2 Effects of SF6 by-products on health
113 C.2.3 Quantitative estimation of gaseous byproducts
Table C.1 – OELs for SO2, HF, and S2F10
Table C.2 – SOF2 production rate
114 C.2.4 Procedures for health risk evaluation
115 Figure C.1 – Procedure for the evaluation of the potential effectson health due to arcing
116 C.3 Conclusion
Figure C.2 – Procedure for the evaluation of the potential effects on health dueto low energy discharges
118 Annex D (informative) Reclaiming recommendations
D.1 General
D.2 Filtering recommendations
D.3 Transport of used SF6 in gas cylinders and containers by road
119 Annex E (informative) Cryogenic reclaiming of SF6
E.1 General
E.2 Applications
E.3 Physical background
Figure D.1 – Saturated vapour pressure of various gases as a function of temperature
120 E.4 Cryogenic processes
E.5 Description of a cryogenic reclaimer
121 Figure D.2 – Typical cryogenic reclaimer for SF6 recovery on site
Figure D.3 – Typical cryogenic reclaimer for removing contaminants
123 Bibliography
BS EN IEC 60480:2019 - TC
$258.95