ISO 11235:2016
$36.40
Rubber compounding ingredients — Sulfenamide accelerators — Test methods
Published By | Publication Date | Number of Pages |
ISO | 2016-01 | 32 |
ISO 11235:2016 specifies the methods to be used for the evaluation of sulfenamide accelerators:
– MBTS: benzothiazyl disulphide;
– CBS: N-cyclohexylbenzothiazole-2-sulfenamide;
– TBBS: N-tert-butylbenzothiazole-2-sulfenamide;
– DIBS: N,N'-diisopropylbenzothiazole-2-sulfenamide;
– DCBS: N,N'-dicyclohexylbenzothiazole-2-sulfenamide;
– MBS: N-oxydiethylenebenzothiazole-2-sulfenamide.
NOTE Although MBTS is not a sulfenamide, it is the primary decomposition product of these accelerators and quantitatively determined by the method specified in 5.2.
The analytical methods are applicable for most commercial sulfenamide accelerators:
– sulfenamides of primary amines (type I);
– sulfenamides of unhindered secondary amines (type II);
– sulfenamides of hindered secondary amines (type III).
The method (5.2) to determine purity by high performance liquid chromatography (HPLC) is the preferred method.